Dichlorido(4,5-diazafluoren-9-one-κ2 N,N′)palladium(II)
نویسندگان
چکیده
The structure of the title compound, [PdCl(2)(C(11)H(6)N(2)O)], shows a nearly square-planar geometry for the Pd(II) atom within a Cl(2)N(2) donor set.
منابع مشابه
Tetraaqua(4,5-diazafluoren-9-one-κ2 N,N′)nickel(II) dinitrate
The title compound, [Ni(C(11)H(6)N(2)O)(H(2)O)(4)](NO(3))(2), was prepared by the reaction of Ni(NO(3))(2) and 4,5-diaza-fluoren-9-one (dafo). The crystal packing consists of a three-dimensional network via O-H⋯O hydrogen bonds between the coordin-ated water mol-ecules and the nitrate anions. The Ni atom lies on a special position (Wyckoff position 4e, site symmetry 2), as does the carbonyl O a...
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In the title compound, [Hg(NCS)(2)(C(11)H(6)N(2)O)], the Hg(II) atom, lying on a twofold rotation axis, is four-coordinated in a distorted tetra-hedral geometry by an N,N'-bidentate diaza-fluoren-9-one ligand and two thio-cyanate anions. In the crystal, inter-molecular C-H⋯N and C-H⋯O hydrogen bonds are effective in the stabilization of the structure.
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In the title complex, [Co(NCS)(2)(C(3)H(4)N(2))(2)(C(11)H(6)N(2)O)], the Co(II) atom has a distorted octa-hedral coordination with the N atoms of the 4,5-diaza-fluoren-9-one ligand and two N atoms from imidazole ligands in the equatorial positions and the axial sites occupied by two N atoms of the thio-cyanate ligand. Inter-molecular N-H⋯O hydrogen bonding forms a one-dimensional motif parallel...
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The title complex, [PdCl(2)(C(21)H(20)N(2))], contains a Pd(II) atom in a slightly distorted square-planar coordination environment defined by two N atoms from one 2,4,6-trimethyl-N-[phen-yl(2-pyrid-yl)methyl-idene]aniline ligand and two Cl atoms, forming a five-membered ring (N-Pd-N-C-C).
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